Please use this identifier to cite or link to this item: http://dspace.aiub.edu:8080/jspui/handle/123456789/183
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dc.contributor.authorIslam, Saiful-
dc.contributor.authorAlfaruqi, Muhammad Hilmy-
dc.contributor.authorPutro, Dimas Yunianto-
dc.contributor.authorMathew, Vinod-
dc.contributor.authorKim, Sungjin-
dc.contributor.authorJo, Jeonggeun-
dc.contributor.authorKim, Seokhun-
dc.contributor.authorSun, Yang-kook-
dc.contributor.authorKim, Khwangho-
dc.contributor.authorKim, Jaekook-
dc.date.accessioned2021-11-01T05:00:06Z-
dc.date.available2021-11-01T05:00:06Z-
dc.date.issued2018-04-30-
dc.identifier.citation36en_US
dc.identifier.issn1864-5631-
dc.identifier.urihttp://dspace.aiub.edu:8080/jspui/handle/123456789/183-
dc.description.abstractRechargeable hybrid aqueous batteries (ReHABs) have emerged as promising sustainable energy-storage devices because all components are environmentally benign and abundant. In this study, a carbon-wrapped sponge-like Na3V2(PO4)3 nanoparticle (NVP@C) cathode is prepared by a simple pyrosynthesis for use in the ReHAB system with impressive rate capability and high cyclability. A high-resolution X-ray diffraction study confirmed the formation of pure Na ion superionic conductor (NASICON) NVP with rhombohedral structure. When tested in the ReHAB system, the NVP@C demonstrated high rate capability (66 mAh g−1 at 32 C) and remarkable cyclability over 1000 cycles (about 72 % of the initial capacity is retained at 30 C). Structural transformation and oxidation change studies of the electrode evaluated by using in situ synchrotron X-ray diffraction and ex situ X-ray photoelectron spectroscopy, respectively, confirmed the high reversibility of the NVP@C electrode in the ReHAB system through a two-phase reaction. The combined strategy of nanosizing and carbon-wrapping in the NVP particles is responsible for the remarkable electrochemical properties. The pyrosynthesis technique appears to be a promising and feasible approach to prepare a high-performance electrode for safe and low-cost ReHAB systems as nextgeneration large-scale energy storage devices.en_US
dc.language.isoenen_US
dc.publisherWiley-VCHen_US
dc.subjectNVP, Hybrid ion batteriesen_US
dc.titlePyrosynthesis of Na3V2(PO4)3@C Cathodes for Safe and Low‐Cost Aqueous Hybrid Batteries.en_US
dc.typeArticleen_US
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